- The elements in Group 17 are : Fluorine, Chlorine, Bromine, Iodine, Astatine.
- This elements are known as halogens.
- This is because halogens are reactive non-metals.
- Halogens exist as diatomic covalent molecules.
- The electronegativity of an element is a measurement of the strength of its atom in a molecule to pull electrons towards its nucleus.
- Halogens are very electronegative.
- Table below shows the electonegativities of halogens.
ElementFluorineChlorineBromineIodineElectronegativity (Pauling scale)4.03.02.82.5
- The electronegativity of halogens decreases when going down the group.
- This is because the number if shells occupied with electrons in the atoms if halogens increases when going down the group.
- This causes the outermost occupied shell to become further away from the nucleus and is screened by more inner shells containing electons
- Hence, the strength of the nucleus to attract electrons becomes weaker.
- Table below shows some physical properties of Group 17 elements.
ElementFluorineChlorineBromineIodineProton number9173553Atomic radius (nm)0.0710.0990.1140.133
- Table below shows the physical state and colours of various halogen.
HalogenPhysical state and colourFluorinePale yellow gasChlorineGreenish-yellow gasBromineReddish-brown liquidIodinePurplish-black solid
- All halogen have low melting and boiling points
- This is because the halogen molecules are held together by weak van der Waals forces of attraction.
- Hence, the small amount of heat energy is needed to overcome it during melting or boiling.
- All halogens have low densities.
- All halogens do not conduct electricity.
- All halogens are weak conductors of heat.
- Table below shows the electron arrangements of halogen.
ElementElectron arrangementFluorine2.7Chlorine2.8.7Bromine2.8.18.7Iodine2.8.18.18.7Astatine2.8.18.32.18.7
- All halogen exhibit similar chemical properties because all the atoms of halogens have 7 valence electrons.
- The reactivity of halogens decreases when going down Group 17.
- The reactivity of a halogen is measured by the ease of its atom to accept one electron so as to achieve a stable noble gas electron arrangement
- When going down Group 17, the atomic size of halogen increases.
- The outermost occupied shell becomes further away from the nucleus and is screened by more inner shells containing electrons.
- This mean that the effective nuclear charge exerted on the outer valence shell decreases when going down the group.
- Therefore, the strenght of the nucleus of a halogen atom to attract one more electron into the valence electron into the valence shell to achieve an octet electron arrangement decreases.